Sodium polyaspartate

Sodium polyaspartate is a condensation polymer based on the amino acid aspartic acid.

Polymerization

The polymerization reaction is an example of a step-growth polymerization to a polyamide and in one practical procedure[1] aspartic acid is simply heated to 180 °C resulting in water release and the formation of a poly(succinimide) with succinimide repeating units. In the subsequent step this polymer is reacted with sodium hydroxide in water which results in partial cleavage of the amide bonds. Two different bonds (α and β) are hydrolyzed resulting in a sodium poly(aspartate) copolymer with 30% α-linkages and 70% β-linkages.

Uses

This material can be synthesized in an environmentally friendly way and is biodegradeable, thus it is a green alternative to several materials such as sodium polyacrylate used in disposable diapers and agriculture.[2][3]

In addition and due to its water-solubility and ability to chelate metal ions, polyaspartate is used as a biodegradeable anti-scaling agent and a corrosion inhibitor.[4][5]

References